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PAGE 8 / NATIONAL CLOTHESLINE / JANUARY, 2021
              THE SPOTTING BOARD                                                                                    BY DAN EISEN











          Using acids and alkali for problems




                 any garments received  removed by drycleaning sol-  alcohol which is subsequently   (4) Neutralize alkali. All al-  (8) Mechanical Action.
                 by my analysis service  vents.                      generated into acetic acid. The  kalis should be neutralized   (9) Flush.
          M(International       Inde-                                hero of the fermentation  after use to prevent yellowing.    (10) Oxalic acid (Test).
          pendent Garment  Analysis    Acids                         process is acetobacter, a small   (5)  Shrunken  leather.    (11) Heat.
          Service by Daniel Eisen) require   Acid is defined as a chemical  microorganism that has the  Caused by heat, can often be   (12) Flush.
          use of acids and alkalis for their  that releases hydrogen ions in  chemical power to transform  corrected by spraying with   (13) Rust Remover (Test).
          correction. Some examples of  the presence of water. We meas-  alcohol into acetic acid. Acetic  acetic acid which will make it   (14) Flush.
          problem solving may be:      ure acids using the pH scale.  acid gives vinegar its pungent  soft and pliable so it can be   (15) Peroxide plus ammonia
             (1) Restoring color to acetate   Seven is neutral and less than  odor. Acetic acid has proper-  shaped. Additional  leather  (Test).
             (2) Correcting shrunken  seven measures the strength of  ties and advantages not pos-  sprays must be used after-    (16) Flush.
          leather                      the acid. The lower number on  sessed by other acids.      wards.                          (17) Acetic Acid.
             (3) Restoring color change   the pH scale indicates a stronger   Acetic acid should be pur-  (6) Add acetic acid to wet-  (18) Flush.
             (4) Removing shine        acid. Acids are safer on bright  chased at 28%. Concentrations  cleaning detergents for setting
             (5) Removing ground-in soils   colors than alkalis and it is for  over 28% will discolor dyes on  dyes on color sensitive fabrics   Alkali
             (6) Prevention of bleeding  that reason we use acids to sta-  fabrics and even dissolve ac-  during wetcleaning proce-  Alkali releases hydroxyl
          during wetcleaning           bilize dyes in wetcleaning.  etate fabrics. It can be pur-  dures.                      ions in the presence of water.
             (7) Expanded stain removal   Strong acids can affect dyes and  chased in concentrations of 56   (7) Use acetic acid to neu-  Alkali on the pH scale is above
             (8) Aid to bleaching      the strength of many fabrics.  or 99% but is not recom-    tralize the following bleaches  seven. The higher the number
             (9) Stretching wool       Prepared tannin formulas are  mended since mixing and di-  — peroxide and ammonia,  the stronger the alkali. Alkali is
             Most spotters use acids and  made up of a mild acid and lu-  luting with water may not be  sodium perborate and sodium  found in protein formulas and
          alkalis in limited use. They may  bricant. This is effective for re-  accurate. Use 28% and even di-  percarbonate.  Acetic acid is  ammonia. Alkali is effective on
          use tannin and protein formulas   moval of many tannin stains or  lute it with more water so it  used to accelerate chlorine  protein stains or stains origi-
          and rust remover but they limit  vegetable-based staining such  can be used in the 20% range.   bleaches and all reducing  nating from the body. This in-
          their potential for problem solv-  as coffee, tea, soda, beer, wine,                    bleaches.                    cludes eggs, milk, urine, etc.
          ing. Acids and alkalis are differ-  etc. The degree of stain removal   Uses of Acetic Acid    (8) Stretching wools. Acetic  The wool and silk are sensitive
          ent in their chemical makeup  can be expanded when the spot-  (1) Use acetic acid after  acid can be added to a cationic  to alkali.
          and they must be used on spe-  ter uses other acids for stain re-  using a tannin formula. Acetic  detergent  in  soaking  a
          cific staining. Spotters must be   moval.                  acid will have a greater effect  shrunken wool that has to be   Protein Formulas
          aware of their potential to dam-                           on many tannin stains espe-  made soft enough to stretch.    Most commercial protein
          age fabrics and color on fabrics.   Acetic Acid            cially wine.                    (9) Acetic acid can be used  formulas are made up of a
          Acids and alkalis neutralize    Acetic acid should be        (2) Delustering of acetate.  in combination with hydrogen  mild alkali and lubricant.
          each other. This means if an al-  added to the spotters arsenal  Acetate fabric damage by heat  peroxide (peracetic) for bleach-
          kali is put on the fabric followed  for stain removal. Acetic acid is  and moisture can often be cor-  ing some fabrics.   Ammonia (26)
          by an acid, the result of the  similar to vinegar. Vinegar is  rected by spraying with acetic                           Ammonia is a very volatile
          chemical reaction would be  produced by the action of bac-  acid, hanging to dry and then   Oxalic Acid              alkali and is stronger than the
          water and salt. This is also true  teria  on  yeast-fermented  cleaning.                   Oxalic acid comes in crystal  alkali found in most protein
          if an acid is put on the fabric fol-  brews. Vinegar can be made   (3)  Shine. Shine on gabar-  or liquid state. Laidlaw makes  formulas.  Ammonia is effec-
          lowed by an alkali. Acids and al-  out of just about any plant that  dine can often be corrected by  a product called Rustgo which  tive for neutralizing the effects
          kalis are water soluble and not  can be fermented to generate  spraying with acetic acid.   is oxalic acid in a liquid form.  of discolorations caused by
                                                                                                  In crystal form the oxalic acid  acids. This usually occurs on
                                                                                                  should be mixed 15 parts  cottons, rayons and linens.
                                                                                                  water to one part oxalic acid.  Sometimes titanium sulphate
                                                                                                  Oxalic acid can be used after  will produce a discoloration
                                                                                                  acetic acid for tannin stain re-  that can be neutralized by
                                                                                                  moval. It will remove rust  using ammonia. For removing
                                                                                                  staining without the damage  ground-in soil nothing works
                                                                                                  potential of rust remover. Ox-  better than using ammonia
                                                                                                  alic acid is applied to a stain  mixed with a wetside lubri-
                                                                                                  and heated with the stream  cant. Ammonia is very volatile
                                                                                                  gun. It must be flushed after  and should be kept in a cool
                                                                                                  use. Remember, heat acceler-  place since it can expand rap-
                                                                                                  ates all chemicals and oxalic  idly. Ammonia is used to in-
                                                                                                  acid should be tested for safety  crease the bleaching action of
                                                                                                  prior to its use on fabrics.   peroxide, perborate and per-
                                                                                                                               carbonate. Do not use ammo-
                                                                                                  Rust Remover                 nia on chlorine bleach since it
                                                                                                    Hydrofluoric acid is the  will break down and will re-
                                                                                                  makeup of rust remover. This  lease chlorine gas.
                                                                                                  is a very effective acid but re-
                                                                                                  quires skill and knowledge for   Protein Spotting Procedure
                                                                                                  its use. Rust remover can be    (1) Flush.
                                                                                                  very corrosive if left on a fabric   (2) Protein formula.
                                                                                                  and contact on a customers      (3) Mechanical action.
                                                                                                  skin can cause severe burns.    (4) Flush.
                                                                                                  After using rust remover it     (5) Ammonia plus neutral
                                                                                                  must be flushed thoroughly  lubricant.
                                                                                                  with water and a protein for-   (6) Mechanical action.
                                                                                                  mula or a mild alkali must be   (7) Flush.
                                                                                                  added to the area to neutralize   (8) Peroxide Plus Ammonia
                                                                                                  any residue the acid left. Rust  (Test).
                                                                                                  remover must be tested before   (9) Heat.
                                                                                                  use and can discolor cashmere,   (10) Flush.
                                                                                                  gabardine, glass trimming and    (11) Acetic Acid.
                                                                                                                                  (12) Flush.
                                                                                                  Tannin Process                  (13) Digest.
                                                                                                     (1) Flush.                Dan Eisen, former chief garment
                                                                                                     (2) Neutral Lubricant.    analyst for the National Cleaners
                                                                                                     (3) Mechanical Action.    Association, can be reached at
                                                                                                     (4) Flush.                (772) 340-0909 or (772) 579-
                                                                                                     (5) Tannin formula.       5044,    by     e-mail   at
                                                                                                     (6) Mechanical Action.    [email protected]     or
                                                                                                     (7) Acetic acid plus neutral   through his website at www.gar-
                                                                                                  lubricant.
                                                                                                                               mentanalysis.com.
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